石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (9): 33-39.

• 加工工艺 • 上一篇    下一篇

变压器油固定床脱水工艺的开发

李萌1,孟繁羽2,吴海燕1,沈娟1,刘乃旺2   

  1. 1. 中国石化润滑油有限公司华东分公司
    2. 华东理工大学化工学院
  • 收稿日期:2021-12-28 修回日期:2022-05-06 出版日期:2022-09-12 发布日期:2022-08-24
  • 通讯作者: 刘乃旺 E-mail:liunw@ecust.edu.cn

DEVELOPMENT OF DEHYDRATION PROCESS FOR TRANSFORMER OIL IN FIXED BED

  • Received:2021-12-28 Revised:2022-05-06 Online:2022-09-12 Published:2022-08-24

摘要: 针对变压器油真空滤油工艺的诸多不足,探索将常温常压固定床吸附技术用于变压器油脱水的可行性,并考察了改性树脂、5A分子筛、活性炭、硅胶等吸附材料的性能。结果表明:在考察的吸附材料中,改性树脂脱水剂的性能最优,无水氯化钙次之,硅胶和5A分子筛的性能最差;当原料变压器油水质量分数为33 μg/g时,在质量空速30 h-1条件下进行固定床吸附脱水后,变压器油初期水质量分数达10 μg/g以下;以固定床出口变压器油水质量分数大于20 μg/g为脱水剂失活标准,新鲜改性树脂脱水剂的吸附容量为96.03 mg/g;吸水改性树脂可多次再生循环利用,再生后改性树脂脱水剂的吸附容量轻微下降。

关键词: 变压器油, 水吸附, 固定床, 脱水剂, 改性树脂

Abstract: In view of the many shortcomings of the vacuum filtering technology for transformer oil, the feasibility of applying the fixed bed adsorption process at room temperature and normal pressure to the dehydration of transformer oil was explored, the performance of different materials such as modified resin, 5A zeolite, activated carbon, and silica gel was investigated. The results showed that the performance of modified resin dehydrating agent was the best, followed by the anhydrous calcium chloride, the silica gel and 5A zeolite. When the water content of the feed oil was 33 μg/g, the initial water content at the outlet was less than 10 μg/g after fixed bed adsorption dehydration at WHSV of 30 h-1. If taking the water content higher than 20 μg/g as the deactivation standard, the adsorption capacity of fresh modified resin was 96.03 mg/g. The modified resin could be used for many times, but the adsorption capacity would be lightly decreased after regeneration.

Key words: transformer oil, water adsorption, fixed bed, dehydrating agent, modified resin