石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (9): 40-43.

• 加工工艺 • 上一篇    下一篇

费-托合成蜡加氢异构生产的 Ⅲ类基础油低温性能研究

王泽爱,黄小珠,黄波,陈远庆,张浩   

  1. 中海油惠州石化有限公司
  • 收稿日期:2022-01-26 修回日期:2022-05-23 出版日期:2022-09-12 发布日期:2022-08-24
  • 通讯作者: 黄小珠 E-mail:huangxzh1@126.com

STUDY ON LOW TEMPERATURE PROPERTY OF API III BASE OIL PORDUCT FROM HYGROISOMERIZATION OF FISCHER-TROPSCH SYNTHETIC WAX

  • Received:2022-01-26 Revised:2022-05-23 Online:2022-09-12 Published:2022-08-24

摘要: 基于工业生产API Ⅱ类润滑油基础油的加氢异构/加氢精制工艺及参数,以及适宜加工费-托合成蜡为原料的催化剂,在200 mL加氢中试装置上进行了费-托合成蜡为原料和工艺参数对API Ⅲ类5cSt润滑油基础油浊点和倾点的影响研究。结果表明:高异构化反应温度、低异构化反应压力以及低碳数的费-托合成蜡为原料,均有助于5cSt润滑油基础油浊点和倾点的降低;以碳数大于40的烃类比例不超过0.5%的费-托合成蜡为原料时,在压力2.5 MPa、温度348 ℃的异构化反应条件下,5cSt润滑油基础油的浊点和倾点分别不高于-15 ℃和-30 ℃,黏度指数不低于135,收率不低于30%。

关键词: 费-托合成蜡, 加氢异构, 润滑油基础油, 低温性能

Abstract: Based on the process and parameters of the hydroisomerization/hydrofining in industrial production of API Ⅱ base oil and catalysts suitable for the processing of Fischer-Tropsch synthetic wax, the influence of Fischer-Tropsch synthetic wax as raw material and process parameters on the cloud point and pour point of API Ⅲ 5cSt base oil were studied in the 200 mL hydrogenation pilot plant. The results showed that high hydroisomerization temperature, low hydroisomerization pressure and low carbon number of Fischer-Tropsch synthetic wax could reduce the cloud point and pour point of 5cSt base oil. When Fischer-Tropsch synthetic wax was used as raw material, the proportion of hydrocarbons with carbon number more than 40 did not exceed 0.5%, the isomerization pressure was 2.5 MPa, and the temperature was 348 ℃, the cloud point and pour point of 5cSt base oil were not higher than -15 ℃ and -30 ℃ respectively, the viscosity index was not lower than 135, and the yield was not lower than 30%.

Key words: Fischer-Tropsch wax, hydroisomerization, lube base oil, low temperature property