石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (4): 106-113.
• 节能减排 • 上一篇 下一篇
李彤,张峰,詹有福
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摘要: 初步分析了催化裂化装置中氮氧化物(NOx)的形成机理,详细探讨了影响再生烟气中NOx含量的因素,并在快速床-湍流床催化裂化再生工艺装置上进行工业试验,分析再生烟气温度、组分含量的交互作用,总结了再生工艺过程中NOx的生成规律。通过改变再生器中的O2、CO含量和串联再生器的各段温度等工艺条件,成功实现了对再生烟气中NOx含量的有效控制,形成了高效、低成本的NOx含量控制技术,指导再生工艺操作。在当前节能、减排的背景下,有望为降低催化裂化再生烟气污染物排放提供一种可替代的技术方案。
关键词: 催化裂化, 快速床-湍流床, 再生工艺, 烟气, 氮氧化物
Abstract: The formation mechanism of nitrogen oxide (NOx) in catalytic cracking device was preliminarily analyzed, the factors affacting NOx content in regeneration flue gas were discussed in detail, and the industrial test of the fast-bed - turbulent bed regeneration process was carried out. The interaction of the temperature and component content of the regenerated flue gas was analyzed, and the rule of NOx formation in the regeneration process was summarized. Effective control of NOx content in the regeneration flue gas was achieved by changing the process conditions such as O2 and CO content in the regenerator and the temperature of each section of the regenerator in series. The high-efficiency and low-cost control technology of NOx content was formed to guide the operation of regeneration process. Under the background of energy saving and emission reduction, it was expected to provide an alternative technology for reducing the pollutant emission from FCC regeneration flue gas.
Key words: catalytic cracking, fast bed-turbulent bed, regeneration process, flue gas, nitrogen oxides
李彤 张峰 詹有福. 快速床-湍流床催化裂化再生装置工艺参数对烟气中氮氧化物生成的影响[J]. 石油炼制与化工, 2023, 54(4): 106-113.
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