石油炼制与化工 ›› 2023, Vol. 54 ›› Issue (4): 15-18.

• 催化剂 • 上一篇    下一篇

PCA-101环保型多功能助剂在催化裂化装置的工业应用

沈兴1,胡晓荣1,夏建平1,李博2,侯凯军2,彭威3   

  1. 1. 中国石油呼和浩特石化公司
    2. 中国石油石油化工研究院兰州化工研究中心
    3. 中国石油大学(北京)克拉玛依校区
  • 收稿日期:2022-10-24 修回日期:2022-12-28 出版日期:2023-04-12 发布日期:2023-04-27
  • 通讯作者: 沈兴 E-mail:shenxhsh@petrochina.com.cn

COMMERCIAL APPLICATION OF ENVIRONMENT-FRIENDLY MULTIFUNCTIONAL ADDITIVE PCA-101 IN CATALYTIC CRACKING UNIT

  • Received:2022-10-24 Revised:2022-12-28 Online:2023-04-12 Published:2023-04-27

摘要: PCA-101环保型多功能助剂在中国石油呼和浩特石化公司2.80 Mt/a催化裂化装置上进行了工业应用。结果表明:加注PCA-101环保型多功能助剂后,不会对装置在用催化剂造成污染;平衡剂中锑质量分数由2 425 μg/g降低至716 μg/g,实现废催化剂由危险废物向固体废物的转变;轻油收率提高0.49百分点,有效改善产品分布;干气中氢气体积分数从48.92%下降至47.39%,具有良好的抑制Ni污染效果。

关键词: 催化裂化, 多功能助剂, 锑, 镍, 氢气

Abstract: Environment-friendly multifunctional additive PCA-101 was used in the 2.80 Mt/a catalytic cracking unit of PetroChina Huhhot Petrochemical Company. The results showed that the addition of PCA-101 did not cause pollution to the catalyst in the FCC unit. The antimony content in the equilibrium catalyst was reduced from 2 425 μg/g to 716 μg/g, and the waste catalyst was transformed from the dangerous waste to the solid waste. Moreover, the yield of light liquid increased by 0.49 percentage point, which effectively improved the product distribution. The volume fraction of hydrogen in dry gas decreased from 48.92% to 47.39%, which indicated that PCA-101 had a good effect of inhibiting Ni pollution.

Key words: catalytic cracking, multifunctional additive, antimony, nickel, hydrogen