石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (11): 40-46.

• 催化剂 • 上一篇    下一篇

新型丁烯助剂HBC-B在重油选择性催化裂解装置的工业应用

黄长青1,于善青2,严加松2,袁光普1,陈世荣1,成晓洁2,蔡凯2   

  1. 1. 扬州石化有限责任公司
    2. 中石化石油化工科学研究院有限公司
  • 收稿日期:2024-03-11 修回日期:2024-07-22 出版日期:2024-11-12 发布日期:2024-10-29
  • 通讯作者: 于善青 E-mail:yusq.ripp@sinopec.com
  • 基金资助:
    国家重点研发计划

COMMERCIAL APPLICATION OF NOVEL CATALYTIC CRACKING ADDITIVE HBC-B FOR BOOSTING BUTYLENE YIELD

  • Received:2024-03-11 Revised:2024-07-22 Online:2024-11-12 Published:2024-10-29

摘要: 中石化石油化工科学研究院有限公司开发了一种新型的高丁烯选择性催化助剂HBC-B,并在扬州石化有限责任公司重油选择性催化裂解(MCP)装置上进行了工业应用。工业应用结果表明:当HBC-B助剂占系统催化剂藏量的5%时,丁烯收率提高1.47百分点,其中异丁烯收率提高0.34百分点,液化气中丁烯体积分数增加4.05百分点;产品分布改善,液化气收率提高0.55百分点,汽油收率提高0.71百分点,柴油产率降低1.28百分点,油浆和焦炭产率基本相同。工业应用结果证明HBC-B助剂具有优异丁烯选择性和重油转化能力。

关键词: 催化裂解, 催化助剂, 丁烯, 异丁烯

Abstract: A new catalytic cracking additive HBC-B for boosting butylene yield was developed by SINOPEC Research Institute of Petroleum Processing Co., Ltd., and the commercial application was carried out on the maximizing catalytic propylene from heavy oil (MCP) unit of Yangzhou Petrochemical Co., Ltd.. The results showed that butylene yield increased by 1.47 percentage points, isobutylene yield increased by 0.34 percentage point, and the volume fraction of butylene in liquefied petroleum gas (LPG) increased by 4.05 percentage points when HBC-B additive accounts for 5.0% of the catalyst inventory in the system. The product distribution was improved, the yield of LPG increased by 0.55 percentage point, the yield of gasoline increased by 0.71 percentage point, and the yield of light cycle oil decreased by 1.28 percentage points, the yields of slurry and coke were basically the same. The commercial application results showed that HBC-B additive had excellent butylene selectivity and heavy oil cracking ability.

Key words: deep catalytic cracking, aid catalyst, butylene, isobutylene