石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (3): 148-153.

• 综述 • 上一篇    下一篇

二氧化硅包覆核壳结构催化剂的制备与应用研究进展

代巧玲,孙佳新,贾燕子,胡大为   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2023-06-27 修回日期:2023-09-26 出版日期:2024-03-12 发布日期:2024-02-28
  • 通讯作者: 代巧玲 E-mail:daiqiaoling.ripp@sinopec.com
  • 基金资助:
    中国石油化工股份有限公司合同项目

RESEARCH PROGRESS ON PREPARATION AND APPLICATION OF SiO2 COATED CORE-SHELL CATALYSTS

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  • Received:2023-06-27 Revised:2023-09-26 Online:2024-03-12 Published:2024-02-28
  • Contact: Qiao-Ling DAI E-mail:daiqiaoling.ripp@sinopec.com

摘要: 核壳材料作为一种复合型高效催化材料,由核心和壳层两部分有序组装而成,表现出优异的协同效应和新特性,在多相催化领域具有广阔的应用前景。其中,SiO2因无毒、化学惰性、光学透明、易于被修饰改性、价格低等优势而成为制备核壳结构催化剂的一种理想的壳层材料。介绍了溶胶-凝胶法、模板剂法、自组装法、表面沉积法等SiO2包覆的核壳结构催化剂的制备方法,并从择形催化、减少活性组分流失、防止纳米颗粒聚集和烧结三方面总结了SiO2包覆的核壳结构催化剂在多相催化中的应用,并探讨了SiO2包覆的核壳结构催化剂的未来发展趋势。

关键词: 核壳催化剂, SiO2包覆, 制备方法, 尺寸选择性, 活性组分, 抗烧结

Abstract: Core-shell materials, as a kind of composite catalyst, are composed of core and shell, which show excellent synergistic effect and new characteristics. SiO2 is an ideal shell material for developing core-shell catalysts because of its advantages such as non-toxicity, chemical inertness, optical transparency, simplicity of modification, and low cost. In this paper, the preparation methods of SiO2 coated core-shell catalysts, including the sol-gel approach, template method, self-assembly process, and surface deposition method were introduced in detail. Besides, the applications of SiO2 coated core-shell catalysts in heterogeneous catalysis, such as shape selective catalysis, reducing the loss of active components, preventing the aggregation of nanoparticles and sintering were discussed. The future development trend of core-shell catalysts coated with SiO2 was pointed out.

Key words: core-shell catalyst, SiO2 coated, preparation method, size selectivity, active component, sintering resistance