石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (3): 27-31.

• 催化剂 • 上一篇    下一篇

PHD-112/PHU-301催化剂级配生产国Ⅵ低凝柴油的首次工业应用

张超群1,范鸣1,杨乾坚1,侯远东2,赵翔1,王培全1   

  1. 1. 中国石油玉门油田炼油化工总厂
    2. 中国石油石油化工研究院
  • 收稿日期:2023-06-12 修回日期:2023-10-08 出版日期:2024-03-12 发布日期:2024-02-28
  • 通讯作者: 杨乾坚 E-mail:3190481@qq.com

THE FIRST APPLICATION OF PHD-112/PHU-301 GRADED CATALYST IN THE PRODUCTION OF CHINA Ⅵ LOW POUR POINT DIESEL

  • Received:2023-06-12 Revised:2023-10-08 Online:2024-03-12 Published:2024-02-28

摘要: 为灵活调整柴汽比,在兼顾冬季多产石脑油的同时生产低凝柴油,中国石油玉门油田炼油化工总厂柴油加氢改质装置选用中国石油石油化工研究院研制的新一代加氢精制催化剂PHD-112与新一代加氢裂化催化剂PHU-301级配生产国Ⅵ低凝柴油。此为该催化剂级配的首次工业应用。装置稳定运行3个月后开展了标定工作,结果表明:采用PHD-112/PHU-301催化剂级配处理催化裂化柴油、焦化石脑油和直馏柴油组成的混合原料,在标定工况下原料油经处理后硫质量分数由4 260 μg/g降至3.6 μg/g,氮质量分数从96 μg/g降低至0.32 μg/g,多环芳烃质量分数降低至6.2%,十六烷指数提高1.6,凝点降至-28 ℃,冷滤点降至-20 ℃,同时增产石脑油10百分点左右(相对进料量)。说明PHD-112/PHU-301催化剂级配的使用性能良好,具有优异的脱硫、脱氮性能以及降凝和增产石脑油的能力,能够满足柴油加氢改质装置生产国Ⅵ低凝柴油的需求。

关键词: 加氢精制, 加氢裂化, 低凝柴油

Abstract: In order to flexibly adjust the ratio of diesel to gasoline and produce low pour point diesel while taking into account the high production of naphtha in winter, a new generation hydrofining catalyst PHD-112 and a hydrocracking catalyst PHU-301, developed by PetroChina Petrochemical Research Institute, were used to produce low pour point diesel in accordance with the standard of China Ⅵ in Refining and Chemical Complex of Yumen Oilfield,PetroChina. After stable operation of the unit for 3 months, calibration work was carried out. The results showed that after the mixture of FCC diesel, coker gasoline, and straight-run diesel was treated with graded PHD-112/PHU-301 catalysts, the sulfur content, nitrogen content and polycyclic aromatic hydrocarbon content of feed oil decreased from 4 260 μg/g to 3.6 μg/g, from 96 μg/g to 0.32 μg/g, and from 18.9% to 6.2% respectively, the hexadecane index increased by 1.6, the condensation point decreased to -28 ℃, and the cold filter point decreased to -20 ℃. At the same time, naphtha yield increased by about 10 percentage points (relative to feed amount), which showed that PHD-112/PHU-301 catalyst had good performance in desulfurization, denitrification, pour point depression and naphtha production. It could meet the production of low pour point diesel with China Ⅵ through diesel hydrotreating unit.

Key words: hydrofining, hydrocracking, low pour point diesel