石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (4): 123-127.

• 设备及防腐 • 上一篇    下一篇

强化硫转移助剂脱硫效率的再生器内构件改造

郗艳龙1,张旭2,刘子龙2   

  1. 1. 中国石化催化剂有限公司
    2. 中国石化石家庄炼化分公司
  • 收稿日期:2023-09-25 修回日期:2024-01-02 出版日期:2024-04-12 发布日期:2024-03-26
  • 通讯作者: 郗艳龙 E-mail:xiyl.chji@sinopec.com

RECONSTRUCTION OF INTERNAL COMPONENTS OF REGENERATOR TO ENHANCE DESULFURIZATION EFFICIENCY OF SULFUR TRANSFER AGENT


  • Received:2023-09-25 Revised:2024-01-02 Online:2024-04-12 Published:2024-03-26

摘要: 某炼化公司2.20 Mt/a重油催化裂化装置检修时,针对单段逆流再生器密相床层中待生催化剂(待生剂)分配不均匀以及气泡相和乳化相传质阻力较大限制硫转移剂脱硫效率的问题,将待生剂分配器由“船”形改为“Y”形,并增加一层Crosser格栅。改造实施后,由于待生剂在密相床层分布得更均匀,使得含SO2的烟气也均匀分布在密相床层,减少了传质阻力,提高了助剂的吸附脱硫效率。在相近的再生工况下,硫转移助剂的捕硫量(PUS)增加了一倍,助剂使用量降低40%,烟气净化系统氨水用量降低40%,助剂费用和运行成本显著降低,同时烟气外观明显改善。

关键词: 催化裂化, 待生剂分配器, 格栅, 硫转移助剂

Abstract: During the maintenance of a 2.20 Mt/a heavy oil catalytic cracking unit in a refining and chemical company, in order to solve the problems of uneven distribution of coked catalyst in the dense phase bed of a single counter-current regenerator and the high resistance of bubble phase and emulsion mass transfer, which limits the desulfurization efficiency of sulfur transfer agent, the spent catalyst distributor was changed from “boat” shape to “Y” shape, and a layer of Crosser grid was added. After remodeling, the SO2-containing flue gas was distributed uniformly in the dense phase bed, which reduced the mass transfer resistance and enhanced the adsorption desulfurization efficiency of the agent. Under similar regeneration conditions, the amount of PUS (pick-up sulfur) of sulfur transfer agent was doubled, the use of additives was reduced by 40%, the ammonia consumption of the flue gas purification system was reduced by 40%, and the cost of additives and the operation cost were significantly reduced. At the same time, the appearance of flue gas was significantly improved.

Key words: catalytic cracking, spent catalyst distributor, grid, sulfur transfer agent