石油炼制与化工 ›› 2024, Vol. 55 ›› Issue (5): 38-44.

• 催化剂 • 上一篇    下一篇

费-托合成油加氢裂化催化剂RCF-1的开发与工业应用

董松涛,李猛,王锦业,梁家林,胡志海,吴昊   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2023-09-27 修回日期:2024-01-22 出版日期:2024-05-12 发布日期:2024-05-06
  • 通讯作者: 董松涛 E-mail:dongst.ripp@sinopec.com
  • 基金资助:
    国家重点研发计划资助

DEVELOPMENT AND COMMERCIAL APPLICATION OF HYDROCRACKING CATALYST RCF-1 FOR FISCHER-TROPSCH SYNTHETIC OIL


  • Received:2023-09-27 Revised:2024-01-22 Online:2024-05-12 Published:2024-05-06
  • Contact: Dong Songtao E-mail:dongst.ripp@sinopec.com

摘要: 为加工费-托合成油,在优化酸性材料的类型、选择合适的介孔硅铝组分的基础上,开发了费-托合成油加氢裂化催化剂RCF-1,该催化剂具有温度敏感性低和中间馏分油选择性高等特点。工业应用结果表明,以RCF-1催化剂为基础,使用低温法费-托合成油加氢提质CFHL技术,异构加氢裂化单元生产的柴油馏分十六烷值为76,凝点为-33 ℃。稳定加氢和异构加氢裂化石脑油馏分适合作为蒸汽裂解料。

关键词: 加氢裂化, 费-托合成油, 柴油, 中间馏分油, 催化剂

Abstract: In order to process Fischer-Tropsch (F-T) synthetic oil, on the basis of optimizing the acidic component of the catalyst to improve the temperature sensitivity of the catalyst and selectingthe suitable mesoporous silica-aluminum components, catalyst RCF-1 for isomerization-hydrocracking of F-T wax was developed,which had low temperature sensitivity and high selectivity of middle-distillate. Based on this catalyst, the low-temperature F-T hydrotreating and hydrofinishing CFHL technology was employed. The commercial application of the catalyst RCF-1 showed that the cetane number and freezing point of the diesel distillate produced by the isomerization-hydrocracking unit were 76 and -33 ℃, respectively,using the low-temperature process for the hydrogenation of F-T synthetic CFHL.The stabilization-hydrogenation and isomerization-hydrocracking naphtha fractions are particularly suitable as steam cracking feed.

Key words: hydrocracking, Fischer-Tropsch synthetic oil, diesel, middle distillate, catalyst