石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (12): 1-5.

• 加工工艺 •    下一篇

苯乙烯焦油催化裂化加工方案研究

陈学峰,张现策,魏晓丽,龚剑洪   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-04-29 修回日期:2025-07-25 出版日期:2025-12-12 发布日期:2025-12-02
  • 通讯作者: 陈学峰 E-mail:chenxf.ripp@sinopec.com
  • 基金资助:
    中国石油化工股份有限公司合同项目

STUDY ON CATALYTIC CRACKING PROCESSING OF STYRENE TAR


  • Received:2025-04-29 Revised:2025-07-25 Online:2025-12-12 Published:2025-12-02

摘要: 为实现催化裂化装置资源化利用苯乙烯焦油,分析了苯乙烯焦油的性质及烃组成特点,考察了苯乙烯焦油催化裂化产物分布特点以及进料方式和掺炼比例对产物分布的影响。结果表明:苯乙烯焦油密度大、残炭高,烃组成以单环芳烃和非稠环的多环芳烃为主;裂化反应产物以汽油和柴油为主,焦炭产率高,汽油中芳烃质量分数在80%以上;苯乙烯焦油适宜采取与催化裂化原料油混合进料且掺炼比例在5%以下的方式加工。

关键词: 苯乙烯焦油, 催化裂化, 汽油

Abstract: In order to realize the resourceful utilization of styrene tar in catalytic cracking unit, the properties and hydrocarbon composition characteristics of styrene tar were analyzed, the product distribution of styrene tar through catalytic cracking and the influence of feeding methods and blending ratios on the product distribution were investigated. The results show that styrene tar has high density, high carbon residue and high aromatics content. The molecular structure of aromatics in styrene tar is dominated by monocyclic aromatics and non-dense polycyclic aromatics. Main products of different styrene tar are gasoline and diesel, with low gas yield and high coke yield, and the aromatics content in gasoline is more than 80%. Based on the influence of product distribution and product quality requirements, styrene tar is suitable for processing by mixing it with catalytic feed and with a blending ratio of less than 5%.

Key words: styrene tar, catalytic cracking, gasoline