石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (6): 100-104.

• 加工工艺 • 上一篇    下一篇

浆态床渣油加氢产品加工路线研究与工业实践

杨庆伟1,任亮2,梁家林2,严张艳2,许月忠1,刘付福千1   

  1. 1. 中国石化茂名分公司
    2. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-02-05 修回日期:2025-02-20 出版日期:2025-06-12 发布日期:2025-05-30
  • 通讯作者: 杨庆伟 E-mail:yangqw.mmsh@sinopec.com

RESEARCH AND COMMERCIAL APPLICATION OF THE PROCESSING ROUTE OF PRODUCTS FROM SLURRY BED RESIDUE HYDROCRACKING UNIT

  • Received:2025-02-05 Revised:2025-02-20 Online:2025-06-12 Published:2025-05-30

摘要: 为了研究浆态床渣油加氢装置产品加工的适宜技术路线,开展了以某石化公司浆态床渣油加氢装置生产的轻油馏分和蜡油馏分为原料,针对多种加工技术方案的中型验证试验,并结合企业实际在工业装置上进行了实践。研究结果表明:轻油馏分经过加氢改质后,可生产得到用作优质催化重整原料的高芳烃潜含量的重石脑油馏分;产品柴油满足国Ⅵ车用柴油标准。蜡油馏分经过浅度脱硫后可以作为船用燃料油调合组分;蜡油馏分经过高压加氢处理后氢质量分数升至12.0%以上,氮质量分数降至500μg/g以下,可以作为优质的催化裂化原料;蜡油馏分通过高压缓和加氢裂化工艺可以转化为优质的催化裂解原料,经过催化裂解技术转化后,乙烯收率达11.74%,丙烯收率达20.65%,三烯(乙烯、丙烯和丁烯)收率达42.62%。工业实践验证了中型试验结果。

关键词: 浆态床, 渣油加氢, 轻油, 蜡油, 加氢改质

Abstract: In order to study the suitable technical route for the processing of products of slurry bed residual oil hydrocracking unit, SINOPEC Maoming Company entrusted SINOPEC Research Institute of Petroleum Processing Co., Ltd. to conduct experiments on various processing technology using the light oil fraction and vacuum gas oil(VGO) fraction produced by the unit as raw materials, and industrial applications have been carried out. The results indicate that after processing through hydroupgrading technology,heavy naphtha oil products is a high-quality heavy feedstock because of the high aromatic potential,the product diesel meets the national Ⅵ standard for automotive diesel. The VGO fraction can be used as a blending component for ship combustion after shallow desulfurization. After high-pressure hydrogenation treatment, the mass fraction of hydrogen of the VGO fraction can be increased to over 12.0%, and the mass fraction of nitrogen can be reduced to less than 500 μg/g. It can be used as a high-quality catalytic cracking feedstock. The VGO fraction can be converted into high-quality catalytic cracking feedstock through high-pressure mild hydrocracking process. After catalytic cracking technology conversion, the ethylene yield is 11.74%, the propylene yield is 20.65%, and the sum of ethylene, propylene, and butene yields is 42.62%. The industrial practice has verified the results of the pilot-scale test.

Key words: slurry bed, residue hydrotreating, light oil, VGO, hydroupgrading