石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (6): 166-174.

• 综述 • 上一篇    

1,2,4-丁三醇催化合成研究进展

刘腾1,张东培1,李霞2,周子淇1,严文娟1,金鑫1,杜峰1,杨朝合1   

  1. 1. 中国石油大学(华东)化学化工学院,重质油全国重点实验室
    2. 青岛琅琊台集团股份有限公司
  • 收稿日期:2024-09-29 修回日期:2025-01-16 出版日期:2025-06-12 发布日期:2025-05-30
  • 通讯作者: 金鑫 E-mail:jamesjinxin@upc.edu.cn
  • 基金资助:
    国家自然科学基金资助项目

RESEARCH PROGRESS ON THE CATALYTIC SYNTHESIS OF 1,2,4-BUTANETRIOL

  • Received:2024-09-29 Revised:2025-01-16 Online:2025-06-12 Published:2025-05-30

摘要: 1,2,4-丁三醇是一种重要的碳四多元醇,在军工、制药和塑料等领域得到了广泛应用。其合成方法主要包括化学合成法、生物发酵法和生物质催化氢解法。传统化学合成法具有工艺简单、产物纯度高等优点,但面临环境污染和资源消耗等问题。生物发酵法以微生物技术为基础,具有环保和可再生的优势,但需关注产率和成本控制。生物质催化氢解法展现出良好的应用前景,然而关于其反应机理和催化剂的研究仍不够深入。为了实现1,2,4-丁三醇的高效绿色合成,未来应着重研究新型催化剂的设计及其构效关系,加速绿色合成工艺的开发。

关键词: 1,2,4-丁三醇, 催化合成, 生物质, 固体酸催化剂

Abstract: 1,2,4-Butanetriol is an important C4 polyol with widespread applications in military, pharmaceutical, and plastic industries. Its synthesis methods primarily include chemical synthesis, microbial fermentation, and catalytic hydrogenolysis of biomass. Traditional chemical synthesis offers advantages such as simplicity in process and high product purity but faces challenges related to environmental pollution and resource consumption. Microbial fermentation, based on microbial technologies, is environmentally friendly and renewable but requires careful attention to yield and cost control. Biomass catalytic hydrogenolysis demonstrates promising application prospects.However, the reaction mechanisms and catalysts in this method remain underexplored. To achieve efficient and sustainable synthesis of 1,2,4-butanetriol, future efforts should focus on the design of novel catalysts and the elucidation of their structure-performance relationships, thereby accelerating the development of green synthetic processes.

Key words: 1,2,4-butanetriol, catalytic synthesis, biomass, solid acid catalyst