石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (6): 58-64.

• 催化剂 • 上一篇    下一篇

DOT-300催化剂在C8+混合芳烃脱烯烃工艺中的应用及效果

刘福泉,张勇,祁磊,苏健,焦晓东,李宗昌,王锋   

  1. 中国石油四川石化有限公司
  • 收稿日期:2024-11-13 修回日期:2024-12-18 出版日期:2025-06-12 发布日期:2025-05-30
  • 通讯作者: 刘福泉 E-mail:tczfsb-5091@163.com

APPLICATION AND EFFECT OF DOT-300 CATALYST FOR REMOVING OLEFIN FROM C8+ AROMATICS

  • Received:2024-11-13 Revised:2024-12-18 Online:2025-06-12 Published:2025-05-30

摘要: 催化重整生成油脱烯烃是保证二甲苯装置进料溴指数符合设计要求的必要操作,而传统白土和改性白土(以下统称白土)脱烯烃存在使用寿命短、换剂频繁、废剂处理污染环境等问题,必须寻找使用寿命长且脱烯烃效果好的替代方案。通过分析和比较主流催化重整生成油液相加氢技术和分子筛催化剂脱烯烃技术的应用和现状,从装置投资和装置应用两个方面考虑,选取分子筛催化剂DOT-300作为替代白土的方案,并对方案应用前后的进料和产品溴指数进行比对分析,验证了分子筛催化剂脱烯烃技术的应用效果,该方案的应用能够保证二甲苯产品溴指数合格的同时保证装置运行稳定,有利于装置长周期运行。

关键词: C8+混合芳烃, 脱烯烃, 分子筛催化剂, DOT-300, 溴指数, 二甲苯

Abstract: Removing olefins from reformate oil is a necessary operation to ensure that the bromine index of xylene feeds meets the design requirements. Traditional clay method have problems such as short service life, frequent change, and environmental pollution. It is necessary to find alternatives with long service life and good effect of deolefin. The application and current situation of mainstream liquid phase hydrogenation technology and molecular sieve catalyst technology for moving olefins were analyzed and compared. Considering the two aspects of device investment and device application, the molecular sieve catalyst DOT-300 was selected as a replacement plan for clay, and the bromine index of the feed and product before and after the application of the scheme was compared. The application effect of molecular sieve catalyst deolefin technology was verified. The application of this scheme can ensure that the bromine index of xylene products is qualified and the stable operation of the device, which is conducive to the long-term operation of the device.

Key words: C8+ aromatics, deolefination, zeolite catalyst, DOT-300, bromine index, xylene