石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (5): 10-17.

• 加工工艺 • 上一篇    下一篇

催化裂化富气和粗汽油脱硫-分离“反序”集成技术研究

毛安国,王文寿,白风宇,张执刚,赵翔宇   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-10-27 修回日期:2025-12-30 出版日期:2026-05-12 发布日期:2026-04-24
  • 通讯作者: 毛安国 E-mail:maoanguo.ripp@sinopec.com
  • 基金资助:
    催化汽油脱硫转化及裂化气脱硫分离一体化技术

STUDY ON THE "REVERSE-ORDER" INTEGRATION FOR THE SEPARATION AND DESULFURIZATION OF FCC WET GAS AND NAPHTHA

  • Received:2025-10-27 Revised:2025-12-30 Online:2026-05-12 Published:2026-04-24

摘要: 基于催化裂化富气和粗汽油先通过吸收稳定单元分离成干气、液化气和稳定汽油,再将干气采用醇胺法脱除硫化氢、液化气采用醇胺法脱除硫化氢和催化氧化法脱除硫醇、稳定汽油采用SZorb吸附脱硫技术脱除硫醇、硫醚和噻吩类硫化物的加工流程,提出了催化裂化富气和粗汽油先采用两个独立反应器集成吸附脱硫,再采用类似催化裂化吸收稳定分离流程,得到精制干气、精制液化气和精制汽油的“反序”集成技术。催化裂化富气和粗汽油分离脱硫“反序”集成技术充分利用SZorb技术脱硫效率高、综合能耗低和催化裂化吸收稳定单元分离精度高、技术成熟的优势,既提高了脱硫效率、简化了生产流程,又提高了精制汽油分离精度和收率、减少了辛烷值损失。采用“反序”集成技术后,精制汽油收率提高0.9百分点,研究法辛烷值提高0.6,可为企业带来显著的经济效益。

关键词: 催化裂化, 富气, 粗汽油, 分离, 脱硫, 反序, 节能降耗

Abstract: Based on the conventional processing flow where fluid catalytic cracking (FCC) wet gas and naphtha are first separated into dry gas, liquefied petroleum gas (LPG), and stabilized gasoline via the absorption-stabilization unit, followed by separate desulfurization. The dry gas is then treated with the alcohol amine method to remove hydrogen sulfide, while the LPG undergoes both the alcohol amine method for hydrogen sulfide removal and catalytic oxidation for mercaptan removal. The stabilized gasoline employs S Zorb adsorptive desulfurization technology to eliminate mercaptans, sulfides, and thiophenic sulfur compounds. A "reverse order" integrated technology was proposed, where FCC wet gas and naphtha first undergo integrated adsorptive desulfurization in two independent reactors, followed by a process similar to FCC absorption-stabilization separation flow, yielding refined dry gas, refined LPG, and refined gasoline. This "reverse order" integrated technology fully leverages the advantages of S Zorb's high desulfurization efficiency, low comprehensive energy consumption, and the high separation precision and mature technology of FCC absorption-stabilization unit. It enhances desulfurization efficiency, simplifies the production process, improves the separation precision and yield of refined gasoline, and reduces octane loss. After adopting the "reverse order" integrated technology, the refined gasoline yield increased by 0.9 percentage point, research octane number rose by 0.6, and the company's economic benefits improved obviously.

Key words: catalytic cracking, wet gas, naphtha, separation, desulfurization, reverse-order, energy conservation and consumption reduction