石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (8): 13-18.

• 加工工艺 • 上一篇    下一篇

直馏柴油加氢裂化装置柴油硫含量超标原因分析及对策

刘志号,魏兰,刘劲松,阿玉艳   

  1. 中国石化北京燕山分公司
  • 收稿日期:2025-01-20 修回日期:2025-04-07 出版日期:2025-08-12 发布日期:2025-07-28
  • 通讯作者: 刘志号 E-mail:16619819320@163.com

ANALYSIS AND COUNTERMEASURES OF EXCESSIVE SULFUR CONTENT IN DIESEL FROM STRAIGHT-RUN DIESEL HYDROCRACKING UNIT


  • Received:2025-01-20 Revised:2025-04-07 Online:2025-08-12 Published:2025-07-28

摘要: 为应对市场需求变化,某炼化企业通过提高直馏柴油加氢裂化装置的加工量来增产精制柴油,然而却出现柴油硫含量异常波动的情况,质量分数最高可达200 μg/g。排查了造成加氢裂化装置精制柴油硫含量超标的原因,如精制反应深度不够、换热器内漏、物料互串、硫化氢脱除不彻底、样品杂质干扰等。结果表明,加工量大幅增加导致管线中低点位置积聚的硫化亚铁杂质扰动,进而导致柴油硫含量超标。通过规范操作参数调整幅度、增加柴油过滤器等一系列控制措施,保证了柴油硫含量稳定合格(质量分数小于3.2μg/g),达到了增产精制柴油的预期目标。

关键词: 柴油, 硫含量, 换热器内漏, 杂质, 过滤器

Abstract: In response to changes in market demand, the straight-run diesel hydrocracking unit increases the production of refined diesel by increasing the processing volume. However, the mass fraction of sulfur of diesel fluctuates abnormally, and it could up to more than 200 μg/g. A series of reasons for the excessive sulfur content of diesel were investigated in detail, such as insufficient depth of refining reaction, internal leakage of heat exchangers, material interconnection, incomplete removal of hydrogen sulfide, sample impurity interference and so on. The results showed that the large changes in diesel flow rate led to the disturbance of ferrous sulfide FeS accumulated in the low point position of the pipeline, which in turn led to the excessive sulfur content of diesel. By adopting a series of control measures such as standard adjustment range of operating parameters and adding a set of diesel filters, it ensured that mass fraction of sulfur in diesel fuel was stable and qualified (< 3.2 μg/g), and the expected goal of increasing the production of refined diesel fuel was achieved.

Key words: diesel, sulfur content, internal leakage of heat exchanger, impurities, filter