石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (1): 44-48.

• 加工工艺 • 上一篇    下一篇

催化裂化装置掺炼焦化蜡油糠醛抽余油的工业实践

李玉博1,吴春元1,陈晓梅1,郗艳龙2,熊逸1   

  1. 1. 盘锦北方沥青燃料有限公司
    2. 中国石化催化剂有限公司
  • 收稿日期:2025-08-19 修回日期:2025-09-10 出版日期:2026-01-12 发布日期:2025-12-23
  • 通讯作者: 李玉博 E-mail:liyubo0818@163.com

INDUSTRIAL PRACTICE OF BLENDING RAFFINATE FROM FURFURAL REFINING OF COKER GAS OIL INTO CATALYTIC CRACKING UNIT

  • Received:2025-08-19 Revised:2025-09-10 Online:2026-01-12 Published:2025-12-23

摘要: 焦化蜡油中碱性氮化物、多环芳烃、胶质和沥青质等含量较高,不利于催化裂化反应的发生。某炼油厂将焦化蜡油糠醛精制后得到的抽余油代替焦化蜡油掺炼至催化裂化装置,结果发现:与焦化蜡油相比,经糠醛精制后,抽余油中碱性氮化物、硫、胶质、芳烃含量均大幅度降低,饱和烃含量增加;掺炼抽余油后,催化裂化装置的原料性质和产品分布得到明显改善;产品中液化气收率提高0.93百分点,汽油收率提高1.08百分点,总液体收率提高0.30百分点,焦炭、油浆、柴油产率降低;干气中氢气与甲烷体积分数降低,表明催化裂化过程中氢利用率提高;液化气中丙烯含量略有升高;汽油辛烷值提高;烟气中NO和SO2含量均下降;催化剂剂耗降低0.3 kg/t,每年可节约催化剂费用350万元。

关键词: 催化裂化, 焦化蜡油, 糠醛精制, 抽余油

Abstract: Coker gas oil contains relatively high concentrations of basic nitrogen compounds, polycyclic aromatic hydrocarbons, resins, and asphaltenes, which are unfavorable for catalytic cracking reactions. A certain refinery substituted coker gas oil with the raffinate obtained after furfural refining of coker gas oil,and blended it into the feed of catalytic cracking unit. This substitution led to a significant improvement in the properties of the feedstock. After furfural refining, the raffinate exhibited substantial reductions in the contents of basic nitrogen compounds, sulfur, resins, and aromatics, along with an increase in the content of saturated hydrocarbons. Following the blending of the raffinate, the product distribution of the catalytic cracking unit showed marked improvements. The yield of liquefied petroleum gas increased by 0.93 percentage points, gasoline yield by 1.08 percentage points, and total liquid yield by 0.30 percentage points, while the yields of coke, slurry oil, and diesel decreased. The volume ratio of hydrogen to methane in the dry gas decreased, indicating enhanced hydrogen utilization efficiency during catalytic cracking. The propylene content in liquefied petroleum gas has slightly increased. The octane number of gasoline increased, and the contents of NOx and SO2 in the flue gas both decreased. Catalyst consumption reduced by 0.3 kg/t, resulting in annual savings of 3.5 million Yuan in catalyst costs.

Key words: catalytic cracking, coker gas oil, furfural refining, raffinate