CO2加氢直接制芳烃双功能催化剂的研究进展

摘要/Abstract

摘要： 对CO2加氢直接制芳烃双功能催化剂的研究为探索以CO₂为碳源合成芳烃提供了新的途径，有助于推动化工行业实现低碳减排和绿色转型。聚焦于CO₂加氢直接制芳烃双功能催化剂的设计与性能优化，旨在通过高效催化剂开发提升CO₂转化率与芳烃选择性。系统分析了甲醇中间体路径与费-托合成路径的协同作用机制，重点探讨了活性中心结构、孔道特性及酸性位点对反应路径的调控作用，明确了金属/分子筛质量比、反应温度等关键参数对产物分布的影响规律。研究结果表明，通过构建具有空间与酸性协同效应的双功能催化剂，可实现CO₂高效转化与芳烃定向合成。未来研究将致力于开发新型多级孔道催化剂体系，推动反应过程动态机理研究与工艺集成优化，为CO₂资源化利用提供技术支撑。

关键词: CO₂加氢, 芳烃, 双功能催化剂

Abstract: Research on bifunctional catalysts for direct hydrogenation of CO₂ to aromatics provides a new approach for exploring the synthesis of aromatics using CO₂ as a carbon source, which is conducive to promoting the low-carbon emission reduction and green transformation of the chemical industry. This work focuses on the design and performance optimization of bifunctional catalysts aimed at enhancing CO₂ conversion efficiency and aromatic selectivity through advanced catalytic material development. A systematic analysis is conducted on the synergistic mechanisms of the methanol-mediated and Fischer–Tropsch synthesis pathways, with particular emphasis on the influence of active site structure, pore architecture, and acid site distribution on reaction pathway regulation. Furthermore, the effects of key operational parameters, such as the metal-to-zeolite mass ratio and reaction temperatureon product distribution are elucidated. The study demonstrates that constructing bifunctional catalysts with spatial and acidic synergistic effects enables both efficient CO₂ conversion and selective aromatics formation. Future research directions will focus on the development of novel hierarchical pore-structured catalyst systems, dynamic mechanistic investigations, and integrated process optimization, providing technological support for CO₂ valorization.

Key words: hydrogenation of CO₂, aromatics, bifunctional catalyst

林强文富利李红伟栾学斌徐润. CO₂加氢直接制芳烃双功能催化剂的研究进展[J]. 石油炼制与化工, 2026, 57(3): 152-165.

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CO₂加氢直接制芳烃双功能催化剂的研究进展

RESEARCH PROGRESS ON BIFUNCTIONAL CATALYSTS FOR DIRECT HYDROGENATION OF CO₂ TO AROMATICS

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