石油炼制与化工 ›› 2025, Vol. 56 ›› Issue (12): 6-14.

• 加工工艺 • 上一篇    下一篇

重质高盐原油脱盐工业试验

钟荣强1,王振宇2,陆语2,杨帆2,郭靖1,贾旭东1,黎志敏1,于丽2,刘玫君2   

  1. 1. 中国石化西北油田分公司
    2. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-04-22 修回日期:2025-08-18 出版日期:2025-12-12 发布日期:2025-12-02
  • 通讯作者: 王振宇 E-mail:wangzy.ripp@sinopec.com

INDUSTRIAL EXPERIMENT ON DESALINATION OF HIGH SALT HEAVY CRUDE OIL

  • Received:2025-04-22 Revised:2025-08-18 Online:2025-12-12 Published:2025-12-02

摘要: 某重质原油含水的矿化度高,导致盐含量高,同时该原油密度高、黏度大、沥青质含量高、固体颗粒含量高,脱水难度较大,导致电脱盐装置脱后原油的盐含量和水含量均较高,影响到企业的安全生产。对该劣质原油性质进行了分析,发现沥青质缩合程度高及固体颗粒物的存在是脱盐困难的重要原因,基于此开发了新型破乳剂RPD-73X和RPD-73Y,使用后大幅降低了电脱盐脱后原油的盐含量和水含量。工业试验结果表明,三级脱后原油盐质量浓度(以NaCl计)平均值为28.5mg/L,与试验前相比下降了41.4%,水质量分数下降了20.1%,表明所研发的破乳剂具有优异的脱盐脱水性能。

关键词: 高盐原油, 脱盐, 破乳, 破乳剂

Abstract: A heavy crude oil with high salt content is due to the high mineralization of its associated water. This crude oil also has high density, viscosity, asphaltene content, and solid particle content, which cause dehydration difficulties. As a result, the low-salinity water injected during the electric desalination process cannot be separated effectively, leading to high salt and water contents in the oil after electric desalination, which affects the enterprise's safe production.By analyzing the properties of this heavy crude oil, it was found that the high condensation degree of asphaltene and the existence of solid particles are the main factors hindering desalination. Accordingly, two demulsifiers, RPD-73X and RPD-73Y, were developed. Their industrial application reduced the salt and water contents in the oil after electric desalination. Industrial test results indicate that after three-stage electric desalination, the average salt mass concentration of the treated crude oil is 28.5 mgNaCl/L, a 41.4% decrease from the pre-test level, while the water mass fraction decreases by 20.1%. These results show that the developed demulsifiers are effective for desalination and dehydration.

Key words: high salt crude oil, desalination, demulsification, demulsifier