石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (4): 9-14.

• 加工工艺 • 上一篇    下一篇

固定床渣油加氢装置催化剂床层径向温差成因及对策

邵志才,刘涛,胡大为,戴立顺   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-09-24 修回日期:2025-12-26 出版日期:2026-05-12 发布日期:2026-04-01
  • 通讯作者: 邵志才 E-mail:shaozc.ripp@sinopec.com

CAUSE AND COUNTERMEASURES OF RADIAL TEMPERATURE DIFFERENCE IN CATALYST BED OF FIXED-BED RESIDUE HYDROTREATING UNIT


  • Received:2025-09-24 Revised:2025-12-26 Online:2026-05-12 Published:2026-04-01

摘要: 以5套固定床渣油加氢装置A,B,C,D,E为对象,考察了固定床渣油加氢装置催化剂床层径向温差成因。结果表明:影响固定床渣油加氢装置催化剂床层物流分布的因素包括入口分配器结构、催化剂特性和催化剂装填质量、液相流体黏度及物流流向。A装置第二周期换用高效分配器后,在原料比第一周期更劣质的情况下,其第一反应器最大径向温差比第一周期低;B装置在第三周期严格控制催化剂装填质量后,在原料比第二周期更劣质的情况下,其第一反应器最大径向温差与第二周期基本一致;随着液相物流黏度降低,C装置反应系列4个反应器催化剂床层最大径向温差依次降低;尽管原料更劣质,E装置两个系列的第一反应器(为滴流床反应器)的催化剂床层最大径向温差均比D装置上行式反应器的催化剂床层径向温差低。针对固定床渣油加氢装置运行过程中催化剂床层径向温差相对稳定及不稳定的情况,分别提出应对措施,若严重影响装置运行还可考虑引入催化裂化柴油在线清洗。

关键词: 固定床, 渣油加氢, 催化剂床层, 径向温差

Abstract: Taking five fixed-bed residue hydrotreating units, A, B, C, D, and E, as the subjects, an investigation was conducted into the causes of radial temperature differences in the catalyst beds of these units. The results show that the factors that affect the flow distribution in the fixed bed residue hydrotreating catalyst bed include inlet distributor, catalyst characteristics and loading efficiency, liquid-phase fluid viscosity, and flow direction. After switching to a high-efficiency distributor in the second run of Unit A, the maximum radial temperature difference of the 1st reactor was lower than that in the first run when the feedstock properties were inferior. After strict control of catalyst loading quality in the third run of Unit B, the maximum radial temperature difference of the 1st reactor was basically the same as that in the second run when the raw material properties were inferior compared to the second run. As the viscosity of the liquid-phase fluid decreases, The maximum radial temperature difference between the catalyst beds of four reactors connected in series in Unit C decreases sequentially. Despite the inferior characteristics of the feedstock, the maximum radial temperature difference between the catalyst beds of the two 1st reactors (trickle bed reactor) in Unit E is lower than that of the catalyst bed of the 1st reactor(up-flow reactor) in Unit D. In response to the relatively stable and unstable radial temperature difference during the operation of the fixed-bed residue hydrotreating unit, countermeasures are proposed. If it seriously affects the operation of the unit, the introduction of FCC light cycle oil online cleaning can also be considered.

Key words: fixed bed, residue hydrotreating, catalyst bed, radial temperature difference